Preheat the oven to 160°C Fan/180°C/350°F and position a rack in the centre of the oven.
Thoroughly spray your bundt pan with non-stick baking spray.
Add chopped chocolate and sliced butter and melt over medium heat.
Sift flour, cocoa powder, espresso powder, baking powder, baking soda and salt in a bowl. Set aside.
In a jug whisk together eggs, buttermilk, vanilla extract , oil and melted chocolate until combined.
Add wet ingredients to the dry ingredients and mix until combined. Be careful not to overmix.
Add hot water and whisk to incorporate.
Pour batter into the bundt tin and bake for 45-50 minutes or until a toothpick inserted into the cake comes out clean with a few crumbs sticking to it.
Leave the cake to cool the cake in the pan for 10 minutes, then turn the cake out onto a plate or cake stand Let the cake cool completely before adding the ganache.